Conversion of Formic Acid into Methanol Using a Bipyridine-Functionalized Molecular Heterogeneous Catalyst
نویسندگان
چکیده
منابع مشابه
Efficient dehydrogenation of formic acid using an iron catalyst.
Hydrogen is one of the essential reactants in the chemical industry, though its generation from renewable sources and storage in a safe and reversible manner remain challenging. Formic acid (HCO(2)H or FA) is a promising source and storage material in this respect. Here, we present a highly active iron catalyst system for the liberation of H(2) from FA. Applying 0.005 mole percent of Fe(BF(4))(...
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Hydrogen has attracted increasing attention as an important alternative secondary energy resource particularly when combined with fuel-cell technology, which may play a very significant role in power generation in the future. Currently most H2 is produced industrially by methane or alcohol reforming and by the water–gas-shift reaction at high temperatures. However, special purification steps ar...
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Catalytic conversion of formic acid into methanol was investigated with Cu as a catalyst and Al as a reductant under hydrothermal conditions. It was found that formic acid can be converted into methanol by such means. The highest yield of methanol (30.4%) was attained with a temperature of 300 °C and a reaction time of 9 h. The AlO(OH) formed from Al oxidation may also play a catalytic role in ...
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Formic acid is a promising energy carrier for on-demand hydrogen generation. Because the reverse reaction is also feasible, formic acid is a form of stored hydrogen. Here we present a robust, reusable iridium catalyst that enables hydrogen gas release from neat formic acid. This catalysis works under mild conditions in the presence of air, is highly selective and affords millions of turnovers. ...
متن کاملSynthesis of Naphthopyranopyrimidines Using Formic Acid as an Effective Catalyst under Solvent-free Conditions
An environmentally friendly, one-pot, three-component synthesis of 8,10-dimethyl-12-aryl-12H-naphtho[1′,2′:5,6]pyrano[2,3-d]pyrimidine-9,11-diones was achieved via coupling aromatic of aldehydes, β-naphthol and 6-amino-1,3-dimethyl uracil in the presence of formic acid as a catalyst under solvent-free conditions at 90 °C. This method has several advantages, such as efficiency, good yield, short...
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ژورنال
عنوان ژورنال: ACS Sustainable Chemistry & Engineering
سال: 2019
ISSN: 2168-0485,2168-0485
DOI: 10.1021/acssuschemeng.8b05070